Difference between revisions of "User:Admin/sandbox"
| Line 17: | Line 17: | ||
*Environmental Organic Chemistry, Chapter 15: Direct Photolysis<ref>Schwarzenbach R.P., Gschwend P.M., and Imboden D.M., 2002. Chapter 15, Direct Photolysis. In: Schwarzenbach R.P., Gschwend P.M., and Imboden D.M. (eds). Environmental Organic Chemistry. 2nd ed. Hoboken, NJ: John Wiley & Sons, Inc, pp. 611-654. [https://doi.org/10.1002/0471649643.ch15 doi:10.1002/0471649643.ch15]</ref> | *Environmental Organic Chemistry, Chapter 15: Direct Photolysis<ref>Schwarzenbach R.P., Gschwend P.M., and Imboden D.M., 2002. Chapter 15, Direct Photolysis. In: Schwarzenbach R.P., Gschwend P.M., and Imboden D.M. (eds). Environmental Organic Chemistry. 2nd ed. Hoboken, NJ: John Wiley & Sons, Inc, pp. 611-654. [https://doi.org/10.1002/0471649643.ch15 doi:10.1002/0471649643.ch15]</ref> | ||
| − | *[//www.enviro.wiki/images/6/64/ERDC2007.pdf Photochemical Degradation of Composition B and Its Components]<ref>Pennington J.C., Thorn K.A., Cox L.G., MacMillan D.K., Yost S., and Laubscher R.D., 2007. Photochemical Degradation of Composition B and Its Components. U.S. Army Engineer Research and Development Center (ERDC)/ Environmental Laboratory (EL) [https://hdl.handle.net/11681/6837 | + | *[//www.enviro.wiki/images/6/64/ERDC2007.pdf Photochemical Degradation of Composition B and Its Components]<ref>Pennington J.C., Thorn K.A., Cox L.G., MacMillan D.K., Yost S., and Laubscher R.D., 2007. Photochemical Degradation of Composition B and Its Components. U.S. Army Engineer Research and Development Center (ERDC)/ Environmental Laboratory (EL) [https://hdl.handle.net/11681/6837 TR-07-16]. [//www.enviro.wiki/images/6/64/ERDC2007.pdf Report]</ref> |
*Verification of RDX Photolysis Mechanism<ref>Peyton G.R., LeFaivre M.H., and Maloney S.W., 1999. Verification of RDX photolysis mechanism. U.S. Army Engineer Research and Development Center (ERDC)/ Construction Engineering Research Laboratory (CERL) | *Verification of RDX Photolysis Mechanism<ref>Peyton G.R., LeFaivre M.H., and Maloney S.W., 1999. Verification of RDX photolysis mechanism. U.S. Army Engineer Research and Development Center (ERDC)/ Construction Engineering Research Laboratory (CERL) | ||
| − | [https://apps.dtic.mil/sti/citations/ADA371755 | + | [https://apps.dtic.mil/sti/citations/ADA371755 TR 99/93]. [//www.enviro.wiki/images/c/ca/ADA1999.pdf Report]</ref> |
| − | *Photochemical transformation of the insensitive munitions compound 2,4-dinitroanisole | + | *Photochemical transformation of the insensitive munitions compound 2,4-dinitroanisole<ref>Rao B., Wang W., Cai Q., Anderson T., and Gu B., 2013. Photochemical Transformation of The Insensitive Munitions Compound 2,4-Dinitroanisole. Science of The Total Environment, 443, pp. 692-699. [https://doi.org/10.1016/j.scitotenv.2012.11.033 doi: 10.1016/j.scitotenv.2012.11.033]</ref> |
*Photo-transformation of aqueous nitroguanidine and 3-nitro-1,2,4-triazol-5-one: Emerging munitions compounds | *Photo-transformation of aqueous nitroguanidine and 3-nitro-1,2,4-triazol-5-one: Emerging munitions compounds | ||
<references /> | <references /> | ||
Revision as of 23:00, 10 December 2021
I have installed SandboxLink extension that provides each user their own sandbox accessible through their personal menu bar (top right)
Munitions Constituents – Photolysis
Munitions compounds (MCs), including 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), 2,4-dinitroanisole (DNAN), 3-nitro-1,2,4-triazol-5-one (NTO), and nitroguanidine (NQ), absorb light in the UV range and are therefore susceptible to photolysis on soil surfaces and in surface water. Photochemical reactions are important to consider when assessing the environmental impact of MCs since they can yield products that differ from their parent compounds in both toxicity and transport behavior. Quantum yield calculations can aid in predicting the photolysis rates and half-lives of MCs. The photolysis of MCs may be enhanced or inhibited in the presence of compounds that are also excited by UV irradiation. Munitions compounds (MCs), including 2,4,6-trinitrotoluene (TNT), hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX), 2,4-dinitroanisole (DNAN), 3-nitro-1,2,4-triazol-5-one (NTO), and nitroguanidine (NQ), absorb light in the UV range and are therefore susceptible to photolysis on soil surfaces and in surface water. Photochemical reactions are important to consider when assessing the environmental impact of MCs since they can yield products that differ from their parent compounds in both toxicity and transport behavior. Quantum yield calculations can aid in predicting the photolysis rates and half-lives of MCs. The photolysis of MCs may be enhanced or inhibited in the presence of compounds that are also excited by UV irradiation.
Related Article(s):
Contributor(s): Dr. Warren Kadoya
Key Resource(s):
- Environmental Organic Chemistry, Chapter 15: Direct Photolysis[1]
- Photochemical Degradation of Composition B and Its Components[2]
- Verification of RDX Photolysis Mechanism[3]
- Photochemical transformation of the insensitive munitions compound 2,4-dinitroanisole[4]
- Photo-transformation of aqueous nitroguanidine and 3-nitro-1,2,4-triazol-5-one: Emerging munitions compounds
- ^ Schwarzenbach R.P., Gschwend P.M., and Imboden D.M., 2002. Chapter 15, Direct Photolysis. In: Schwarzenbach R.P., Gschwend P.M., and Imboden D.M. (eds). Environmental Organic Chemistry. 2nd ed. Hoboken, NJ: John Wiley & Sons, Inc, pp. 611-654. doi:10.1002/0471649643.ch15
- ^ Pennington J.C., Thorn K.A., Cox L.G., MacMillan D.K., Yost S., and Laubscher R.D., 2007. Photochemical Degradation of Composition B and Its Components. U.S. Army Engineer Research and Development Center (ERDC)/ Environmental Laboratory (EL) TR-07-16. Report
- ^ Peyton G.R., LeFaivre M.H., and Maloney S.W., 1999. Verification of RDX photolysis mechanism. U.S. Army Engineer Research and Development Center (ERDC)/ Construction Engineering Research Laboratory (CERL) TR 99/93. Report
- ^ Rao B., Wang W., Cai Q., Anderson T., and Gu B., 2013. Photochemical Transformation of The Insensitive Munitions Compound 2,4-Dinitroanisole. Science of The Total Environment, 443, pp. 692-699. doi: 10.1016/j.scitotenv.2012.11.033
