Long-Term Monitoring (LTM) - Data Analysis

Site managers commonly use long-term monitoring data to assess changes in contaminant concentrations over time. Statistical methods available in a variety of software packages are used to distinguish between real long-term changes in concentration and apparent changes associated with random variation and short-term fluctuations. When quarterly monitoring is conducted, studies suggest that long-term monitoring activities must be conducted for at least 4 years to obtain a moderately accurate evaluation of the long-term concentration change. With less frequent monitoring (i.e., semi-annual or annual), a somewhat longer monitoring period is required. However, this may be balanced by a reduction in the overall cost of the monitoring program.

Related Article(s):

• Long-Term Monitoring (LTM)
• Long-Term Monitoring (LTM) - Data Variability

Contributor(s): Dr. Thomas McHugh and Dr. David Adamson, P.E.

Key Resource(s):

• Groundwater statistics and monitoring compliance, statistical tools for the project life cycle
• Methods for minimization and management of variability in long-term groundwater monitoring results-ER-201209

Introduction

For sites where the initial investigation has been completed and the remedy has been implemented or is under development, the primary objective of continued groundwater monitoring is to track long-term changes in contaminant concentrations. Site managers use these long-term changes to evaluate the effectiveness of site remedies (e.g., natural attenuation or long-duration active remediation such as pump and treat). Other long-term monitoring (LTM) objectives may include protection of a receptor or sentinel well or verification of hydraulic control.

To evaluate remediation progress, a site manager will typically conduct a trend analysis of contaminant concentration vs. time from the monitoring results. A site manager can use the trend analysis to answer two key questions related to groundwater monitoring:

1. Are contaminant concentrations decreasing over time?
2. What is the attenuation rate and when will the site remediation goals be attained?

Analysis Methods

Site managers often use parametric or non-parametric statistica methods to analyze LTM groundwater concentration vs. time data. Parametric statistical methods incorporate specific assumptions regarding the data distribution (e.g., a normal distribution or a log normal distribution), while non-parametric methods do not. Parametric methods are more accurate and powerful for the analysis of datasets that satisfy the specified assumptions. However, non-parametric methods are more accurate for datasets that do not satisfy the required assumptions that are incorporated into the specific parametric methods. Site managers commonly choose between one parametric method (linear regression) and two non-parametric methods (Mann-Kendall and Theil-Sen Slope Estimator) to evaluate concentration trends over time. Mann-Kendall can only be used to evaluate the concentration trend (i.e., are concentrations increasing or decreasing?) with linear regression and the Theil-Sen Slope Estimator can be used to evaluate both concentration trends and attenuation rates. When evaluating concentration vs. time with groundwater monitoring data, the long-term concentration trend is most commonly assumed to be first-order (e.g., exponential decay). This first-order attenuation rate is estimated using linear regression or the Theil-Sen Slope Estimator on natural log transformed concentration data (i.e., Ln(C)) vs. time. The site manager may conduct trend analysis for individual monitoring wells or for the plume as a whole (i.e., using a representation of plume mass or average plume concentration).

Most statistics software packages can be used for parametric or non-parametric trend analysis. In addition, organizations have developed a number of free software programs specifically for analysis of environmental monitoring data (see Appendix D of ITRC, 2013). Commonly used software tools include:

• Microsoft Excel: Parametric trend analyses can be conducted using Excel functions or the Data Analysis Tool Pack add-in that is part of the Excel software package, but may not be installed on your computer if the default installation option was chosen.
• ProUCL (Free): Supports parametric and non-parametric analyses.
• [MAROS (Free): Supports spatial data averaging for whole plume trend analysis.
• Mann-Kendall Tool Kit (Free): Evaluates concentration trends using the Mann-Kendall statistical test.

How Much Data is Needed?

For statistical analyses, more data (e.g., more groundwater monitoring events over a longer time period) yields a more accurate analysis (i.e., a smaller p-value or a smaller [[wikipedia: Confidence interval | confidence interval]). The amount of monitoring data needed to characterize the long-term attenuation rate with a defined level of accuracy (i.e., a confidence interval less than a defined threshold) or confidence (i.e., a p-value less than a defined level) depends on the site-specific long-term attenuation rate and the magnitude of short-term variability. Less data are required for a site with fast attenuation and low short-term variability. More data are required for a site with slow attenuation and high short-term variability.

Table 1. Monitoring data required to determine long-term attenuation rate.

Researchers analyzed historical monitoring records from 20 sites in order to characterize the range of monitoring data requirements at different sites as part of an ESTCP-funded project. At each site, they used historical monitoring data to determine attenuation rate and the site-specific magnitude of short-term variability. Next, they used these values to determine how much monitoring data were required to characterize the long-term attenuation rate within a defined level of accuracy or confidence (Table 1).

This evaluation showed that characterization of long-term trends with either medium confidence or medium accuracy almost always requires four or more years of quarterly monitoring data. The researchers defined medium confidence as a p-value = 0.1, lower than the typical threshold for statistical confidence of 0.05. Longer monitoring times would be required to obtain p-values of 0.05 in most monitoring wells. Additional key findings were:

• It is important to recognize that apparent trends characterized using too little data can be misleading and may result in inappropriate management decisions.
• When evaluating natural attenuation, there are often situations where the project manager can be confident that contaminant concentrations are decreasing, but highly uncertain as to when numerical clean-up goals will be attained.
• For sites with slow attenuation rates, it may be difficult to prove with statistical confidence that contaminant concentrations are decreasing.

Trade-off Between Monitoring Frequency and Duration

Although the absolute time (or number) of monitoring events required to characterize long-term attenuation rate depends on the short-term variability and the attenuation rate, the trade-off between monitoring frequency and time is independent of these parameters. If you reduce monitoring frequency (e.g., from quarterly to semi-annual monitoring), then you need to extend the total monitoring time in order to characterize the long-term attenuation rate with the same level of confidence or accuracy. The trade-off between monitoring frequency and time required to characterize the long-term trend is defined by the mathematics of linear regression and is the same at every site. At all sites, five years of semi-annual monitoring data (10 monitoring events total) provides the same information about the long-term attenuation as four years of quarterly monitoring data (16 monitoring events) regardless of the inherent level of event-to-event variability at the site. Thus, switching from quarterly to semi-annual monitoring will reduce the number of monitoring events needed to characterize the long-term trend by 38%, but the amount of time needed will increase by 25%. The trade-off between monitoring frequency and monitoring duration is summarized in Table 2.

Table 2. Trade-off between monitoring frequency and time. Note: Relative cost is the same as the relative total number of monitoring events required (i.e., based on the assumption that cost is proportional to number of monitoring events) (see McHugh et al., 2006 for derivation of these relationships).

Summary

Site managers can use statistical methods and software tools to analyze long-term groundwater monitoring data. These methods and tools can be used to answer key questions about the long-term trends in these data, such as “are the concentrations decreasing?” and “what is the underlying attenuation rate?” Managers should always consider how much data is needed to address these questions as well as the inherent trade-off between monitoring frequency and duration when considering the data collection strategy.

See Also

• Linear Regression Calculator
  
• The Thiel-Sen Calculator
  
• A-Priori Sample Size For Multiple Regression Calculator
• Adaptive Long-Term Monitoring at Environmental Restoration Sites
• Demonstration and Validation of GTS Long-Term Monitoring Optimization Software at Military and Government Sites